Structural modifications of ZrO2

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Structural and dielectric properties of amorphous ZrO2 and HfO2

Zirconia ZrO2 and hafnia HfO2 are leading candidates for replacing SiO2 as the gate insulator in complementary metal-oxide semiconductor technology. Amorphous versions of these materials a-ZrO2 and a-HfO2 can be grown as metastable phases on top of a silicon buffer; while they tend to recrystallize during subsequent annealing steps, they would otherwise be of considerable interest because of th...

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Fabrication and nano structural study on La2O3-Co3O4-ZrO2 composite

We report on the synthesis, morphology, chemically and structurally of La2O3-Co3O4-ZrO2 nanostructure. The La2O3-Co3O4-ZrO2 nanostructure was synthesized by a method based on the co-precipitation. Composite powders have been characterized by XRD (X-ray diffraction), SEM (scanning electr...

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Structural and dielectric properties of crystalline and amorphous ZrO2

We first review earlier work in which we computed the first-principles structural, vibrational, and lattice dielectric properties of the cubic, tetragonal, and monoclinic phases of ZrO2 and HfO2. We then discuss two approaches to the construction of realistic models of amorphous ZrO2: a bmelt-and-quenchQ ab-initio molecular dynamics approach, and an bactivation–relaxation techniqueQ. The struct...

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Structural Characterization of WO3/ZrO2 Catalysts using HAADF Imaging

Tungsten oxide supported on ZrO2 is receiving increased attention as a solid acid catalyst due to its important industrial applications, such as the isomerization of C4-C8 alkanes to upgrade gasoline octane number. It is known that the catalytic activity depends on the structure of WOx species and their interaction with ZrO2 support [1], so a thorough structural characterization is essential fo...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography

سال: 2002

ISSN: 0108-7673

DOI: 10.1107/s0108767302099324